Image of Neptune's Rings taken from Voyager 2 in 1989.
Three rings are easily seen in this image: Adams (outermost), Le Verrier (middle) and Galle (inner ring). To the left of the image, in the Adams Ring, Galatea is visible. Between Adams and Le Verrier, two faint rings can be made out: Arago and Lassell.
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The Adams Ring is unique in that it contains arcs, which are caused by gravity from Galatea. The arcs were discovered when Neptune occulted a star and where the rings should have been, the star shone through the rings. Close ups by Voyager confirmed that the Adams Ring contained arcs.
Much like the rings around Jupiter, Saturn, and Uranus, the material in the rings of Neptune are not permanent. They are continuously replenished by collisions with the moons of Neptune and are kept in orbit by shepherd satellites. The rings themselves are mostly dust with some ice particles and are covered in organic material (carbon compounds) that make them dark.
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